endo-Norbornene-cis-5,6-dicarboxylic acid - Names and Identifiers
Name | cis-5-Norbornene-endo-2,3-dicarboxylic acid
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Synonyms | 5-Norbornene-2,3-dicarboxylic acid Norbornylene-2,3-Dicarboxylic Acid NORBORNYLENE-2,3-DICARBOXYLIC ACID 5-Norbornene-endo-2,3-dicarboxylic acid endo-Norbornene-cis-5,6-dicarboxylic acid CIS,ENDO-5-NORBORNENE-2,3-DICARBOXYLIC ACID cis,endo-5-Norbornene-2,3-dicarboxylic acid CIS-5-NORBORNENE-ENDO-2,3-DICARBOXYLIC ACID cis-5-Norbornene-endo-2,3-dicarboxylic acid 8,9,10-trinorborn-5-ene-2,3-dicarboxylic acid Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid 3,6-ENDOMETHYLENE-1,2,3,6-TETRAHYDROPHTHALIC ACID EXO,EXO BICYCLO(2.2.1)HEPT-2-EN-5,6-DICARBOXYLIC ACID (2R,3S)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid 3,6-endo-methylenecyclohex-4-ene-1,2-dicarboxylic acid CIS,ENDO-BICYCLO[2.2.1]-5-HEPTENE-2,3-DICARBOXYLIC ACID cis-endo-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid cis,endo-Bicyclo[2.2.1]-5-heptene-2,3-dicarboxylic acid (1S,2R,3S,4S)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate (1R,2R,3S,4R)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate (1R,2S,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid
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CAS | 3853-88-1 3813-52-3
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EINECS | 223-301-0 |
InChI | InChI=1/C9H10O4/c10-8(11)6-4-1-2-5(3-4)7(6)9(12)13/h1-2,4-7H,3H2,(H,10,11)(H,12,13)/t4?,5?,6-,7+ |
endo-Norbornene-cis-5,6-dicarboxylic acid - Physico-chemical Properties
Molecular Formula | C9H10O4
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Molar Mass | 182.17 |
Density | 1.481±0.06 g/cm3(Predicted) |
Melting Point | 175°C (dec.)(lit.) |
Boling Point | 419.8±45.0 °C(Predicted) |
Flash Point | 221.8°C |
Vapor Presure | 3.18E-08mmHg at 25°C |
pKa | 3.91±0.40(Predicted) |
Storage Condition | Sealed in dry,Room Temperature |
Refractive Index | 1.601 |
MDL | MFCD00003735 |
Physical and Chemical Properties |
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endo-Norbornene-cis-5,6-dicarboxylic acid - Risk and Safety
Hazard Symbols | Xn - Harmful
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Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 - Wear suitable gloves and eye/face protection
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
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WGK Germany | 3 |
HS Code | 29172090 |
Hazard Class | IRRITANT |
endo-Norbornene-cis-5,6-dicarboxylic acid - Introduction
cis-5-Norbornene-endo-2,3-dicarboxylic acid(cis-5-Norbornene-endo-2) is an organic compound. The following is a description of its nature, use, formulation and safety information.
Nature:
-Appearance: cis-5-Norbornene-endo-2,3-dicarboxylic acid is a colorless crystalline solid.
-Solubility: Its solubility in water is low, but it is soluble in organic solvents such as ethanol, chloroform and dimethylformamide.
-Melting point: Its melting point range is about 171-173°C.
Use:
cis-5-Norbornene-endo-2,3-dicarboxylic acid has a wide range of applications in organic synthesis, including the following:
-It can be used as an organic synthesis intermediate for the synthesis of other organic compounds.
-As a ligand, it can be used to synthesize metal complexes and catalyze chemical reactions.
-In polymer chemistry, it can be used to prepare high-performance polymers such as polyamide esters, polyimides and polyesters.
Preparation Method:
cis-5-Norbornene-endo-2,3-dicarboxylic acid is usually prepared by the following methods:
-Acid-catalyzed reaction of norbornene (norbornene) and dicarboxylic acid: react norbornene with dicarboxylic acid under acidic conditions to generate cis-5-Norbornene-endo-2 acid, 3-dicarboxylic acid.
Safety Information:
- cis-5-Norbornene-endo-2,3-dicarboxylic acid is generally relatively safe under normal use conditions.
-However, for any chemical, users must follow proper safety procedures, including wearing personal protective equipment (such as glasses, protective gloves, and lab clothes).
-Avoid contact with skin and eyes, and avoid inhaling dust or vapors.
-During use and storage, avoid contact with oxidants and strong acids to avoid possible dangerous reactions.
-In case of discomfort caused by misuse or contact, seek medical advice immediately and present the chemical's safety data sheet.
Last Update:2024-04-09 20:45:29